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UNIT SYLLABUS

E.2 Quantum physics

HL 8 hours · HL only
Three experiments broke classical physics. The photoelectric effect: light below a threshold frequency ejects no electrons no matter how intense — Einstein's explanation, light arrives in quanta of energy $hf$, won him the Nobel Prize. Electron diffraction: particles fired through crystals produce interference patterns, confirming de Broglie's wild proposal that matter has wavelength $\lambda = h/p$. Compton scattering: X-ray photons bounce off electrons like billiard balls, their wavelength shift depending only on angle. Together they force the strangest conclusion in science: light and matter are both waves and particles, revealing whichever face the experiment asks for.

Guiding Questions

  • ? What evidence forces us to accept that light behaves as particles and matter as waves?
  • ? How did quantum theory change our understanding of measurement and prediction?

What the IB expects you to master

  • Describe the photoelectric effect as evidence for the particle nature of light.
  • Explain the threshold frequency: photons need hfΦhf \ge \Phi (the work function) to release photoelectrons.
  • Apply Einstein's photoelectric equation Emax=hfΦE_{max} = hf - \Phi, including stopping-potential measurements.
  • Explain why intensity changes photocurrent but not maximum kinetic energy, while frequency does the reverse.
  • Describe diffraction of electrons as evidence for the wave nature of matter (wave–particle duality).
  • Use the de Broglie wavelength λ=hp=hmv\lambda = \frac{h}{p} = \frac{h}{mv}.
  • Describe Compton scattering as further evidence for photons, and use Δλ=hmec(1cosθ)\Delta\lambda = \frac{h}{m_ec}(1 - \cos\theta).

1 Key Formulas

Photoelectric equation
Emax=hfΦE_{\text{max}} = hf - \Phi
Photon energy
E=hf=hcλE = hf = \frac{hc}{\lambda}
de Broglie wavelength
λ=hp=hmv\lambda = \frac{h}{p} = \frac{h}{mv}
Compton scattering
λλ=hmec(1cosθ)\lambda' - \lambda = \frac{h}{m_{e}c}(1 - \cos\theta)

2 Exam Preparation & Topic Explanations

The photoelectric graph toolkit

The EmaxE_{max} (or stopping potential) versus frequency graph is the unit's centrepiece: gradient = hh (universal, same for every metal), x-intercept = threshold frequency, y-intercept = Φ-\Phi. Different metals give parallel lines. Practise extracting all three from data.

Keep the two duality experiments paired with their conclusions: photoelectric/Compton → light is particles; electron diffraction → matter is waves.

Pro Exam Strategy
  • Work in eV where possible; convert to joules only inside λ=hc/E\lambda = hc/E style calculations.

  • One photon, one electron — the phrase that unlocks most explanation marks.

  • "Stopping potential" numerically equals EmaxE_{max} in eV — a free conversion.

  • de Broglie for accelerated charges: λ=h/2meV\lambda = h/\sqrt{2meV}

    c0,-2,0.3,-3.3,1,-4c1.3,-2.7,23.83,-20.7,67.5,-54

    c44.2,-33.3,65.8,-50.3,66.5,-51c1.3,-1.3,3,-2,5,-2c4.7,0,8.7,3.3,12,10

    s173,378,173,378c0.7,0,35.3,-71,104,-213c68.7,-142,137.5,-285,206.5,-429

    c69,-144,104.5,-217.7,106.5,-221

    l0 -0

    c5.3,-9.3,12,-14,20,-14

    H400000v40H845.2724

    s-225.272,467,-225.272,467s-235,486,-235,486c-2.7,4.7,-9,7,-19,7

    c-6,0,-10,-1,-12,-3s-194,-422,-194,-422s-65,47,-65,47z

    M834 80h400000v40h-400000z"/> — derive it once, reuse forever.

3 MCQ Practice

Q1. Doubling the intensity of light above the threshold frequency shining on a metal surface:

  • Doubles the maximum kinetic energy of the photoelectrons
  • Doubles the number of photoelectrons emitted per second
  • Halves the work function
  • Doubles the stopping potential

Q2. Light of photon energy 3.0 eV strikes a metal of work function 2.0 eV. The stopping potential is:

  • 5.0 V
  • 3.0 V
  • 2.0 V
  • 1.0 V

Q3. An electron and a proton have the same de Broglie wavelength. They must have the same:

  • Speed
  • Kinetic energy
  • Momentum
  • Mass

4 Short Answer Questions

PDF

Download the practice worksheet

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